Predicting the stability of cyclic disulfides by molecular modeling: Effective concentrations in thiol-disulfide interchange and the design of strongly reducing dithiols

JA Burns, GM Whitesides

文献索引：Journal of the American Chemical Society, , vol. 112, # 17 p. 6296 - 6303

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被引用次数: 77

摘要

... 0002-7863/90/ 15 12-6296$02.50/0 0 1990 American Chemical Society ... Chem. SOC., Vol. ... In physical- organic chemistry, the thiol-disulfide interchange reaction is unique in its ability to break and reform strong (-270 kJ/mol), directional covalent bonds reversibly in water at room ...