Hydrogen atom transfer oxidation of primary and secondary alcoholates into aldehydes and ketones by aromatic halides in liquid ammonia. A new electrochemically …

…, J Badoz-Lambling, C Bonnel-Huyghes…

文献索引：Amatore, Christian; Badoz-Lambling, Janine; Bonnel-Huyghes, Claudine; Pinson, Jean; Saveant, Jean Michel; Thiebault, Andre Journal of the American Chemical Society, 1982 , vol. 104, # 7 p. 1979 - 1986

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被引用次数: 31

摘要

Abstract: It is possible to induce the oxidation of alcoholates into the corresponding carbonyl compounds by electrochemical reduction of aromatic halides in liquid ammonia, Le., to electrochemically trigger the reaction ArX+> CH-O--ArH+> C= O+ X-. H-Atom transfer from ...