Singlet dioxygen formation in ozone reactions in aqueous solution

…, E Mvula, SE Braslavsky, C von Sonntag

文献索引：Munoz; Mvula; Braslavsky; Von Sonntag Journal of the Chemical Society, Perkin Transactions 2, 2001 , # 7 p. 1109 - 1116

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被引用次数: 54

摘要

In ozone reactions, singlet dioxygen [O2 (1Δg)] is formed when ozone reacts by O-atom transfer. O2 (1Δg) yields were determined for more than 50 compounds using as reference the reaction of hydrogen peroxide with hypochlorite. Close to 100% yields were found in the reaction of O3 with sulfides, disulfides, methanesulfinic acid, and nitrite. In accordance with this, the only products are: methionine sulfoxide, methanesulfonic acid, and nitrate for the ...