Nucleophilic reactions of anions with trimethyl phosphate in the gas phase by ion cyclotron resonance spectroscopy

…, SA Sullivan, JL Beauchamp

文献索引：Hodges, Ronald V.; Sullivan, S. A.; Beauchamp, J. L. Journal of the American Chemical Society, 1980 , vol. 102, # 3 p. 935 - 938

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被引用次数: 25

摘要

The relationship between the proton affinity and ionization potential revealed in the present study indicates that the proton-affinity order is determined by differences in the abilities of the phosphites to assume a positive charge. This conclusion supports previous rationalizations of the basicity order, in which the trend is ascribed to differences in the interaction of the oxygen lone pairs with phosph~ rus.~~~~~~ The repulsive interaction of the phosphorus ...