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The Journal of Organic Chemistry

Kinetics of methanolysis and of sodium methoxide induced elimination from substituted benzyldimethylcarbinyl chlorides

JF Bunnett, S Sridharan

文献索引:Bunnett,J.F.; Sridharan,S. Journal of Organic Chemistry, 1979 , vol. 44, # 9 p. 1458 - 1463

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被引用次数: 13

摘要

Results From either methanolysis or methoxide-induced elimination, the products are two olefins (2 and 3) and an ether (4). Synthesis of Substrates. Although most of the substrates were obtained straightforwardly, the synthesis of one calls for special comment. p- Nitrobenzyldimethylcarbinyl chloride (If) is conspicuously absent from the reports of Landis and VanderWerfG" and of Brown and Kim. 7 Blackwell et al. 485 mention specifically their ...