Tetrahedron Letters

Electrochemical oxidation of acylsilanes

J Yoshida, S Matsunaga, S Isoe

文献索引：Yoshida, Jun-ichi; Matsunaga, Shin-ichiro; Isoe, Sachihiko Tetrahedron Letters, 1989 , vol. 30, # 39 p. 5293 - 5296

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被引用次数: 26

摘要

Abstract Oxidation potentials of acylsilanes were found to be much less than those of the corresponding ketones and aldehydes. Electrochemical oxidation of acylsilanes resulted in facile cleavage of the carbon-silicon bond and introduction of oxygen and nitrogen nucleophiles at the carbonyl carbon. Therefore acylsilanes serve as a synthetic equivalent of acyl cations.