Derivatives of Piperazine. V. Compounds from N-Phenylpiperazine and Derivatives of Monochloroacetic Acid

DE Adelson, CB Pollard

文献索引：Adelson; Pollard Journal of the American Chemical Society, 1935 , vol. 57, p. 1430

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被引用次数: 1

摘要

Summary 1. Quantitative isotopic exchange reactions have been carried out with free hexoses, their methylglycosides and other derivatives in concentrations of 11-30 and 80- 96% DzO. It is shown that consistent results can be obtained only if the equilibrium constant K for the expression ROH+ HOD e ROD+ HOH is considered explicitly. 3. A common K, numerically 0.65, is used for the calculation of the exchange number of twentyone ...