Organometallics

Low Oxidation State Gallium Compounds Synthesis and Characterization of [Ga (CH2CMe3)] n

OT Beachley Jr, JC Pazik, MJ Noble

文献索引：Beachley, O. T. Jr.; Pazik, John C.; Noble, Matthew J. Organometallics, 1994 , vol. 13, p. 2885 - 2889

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被引用次数: 17

摘要

The new organogallium (1) compound [Ga (CHzCMes) l, has been prepared by the reduction of Ga (CH2CMes) zCl by using either sodium or lithium with naphthalene in THF. When the reagenta were combined at-78 OC, a yellow intermediate, a neopentylgallium (II1) derivative of dihydronaphthalene C& [G~(CH~ CM~ S) ZIZ-~ MC~(M= Li, Na) was formed. Warming of the solution to 0-25 OC resulted in decomposition of the yellow intermediate ...