Dalton Transactions

Magnesium complexes containing biphenyl-based tridentate imino-phenolate ligands for ring-opening polymerization of rac-lactide and α-methyltrimethylene …

W Yi, H Ma

文献索引：Yi, Wei; Ma, Haiyan Dalton Transactions, 2014 , vol. 43, # 13 p. 5200 - 5210

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被引用次数: 21

摘要

A series of racemic 2-[(2′-(dimethylamino) biphenyl-2-ylimino) methyl]-4-R2-6-R1-phenols (L1H–L4H) were reacted with {Mg [N (SiMe3) 2] 2} 2 to provide four heteroleptic magnesium complexes (L1–4) MgN (SiMe3) 2·(THF) n (1, R1= tBu, R2= Me, n= 1; 2, R1= R2= CMe2Ph,