Neighboring Groups in Addition. II. Hydroxyl and Acetoxy Groups in Allyl Derivatives1, 2

S Winstein, L Goodman

文献索引：Winstein; Goodman Journal of the American Chemical Society, 1954 , vol. 76, p. 4368,4371

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被引用次数: 30

摘要

Participation of neighboring groups in the process of addition of an electrophilic reagent to the carbon-carbon double bond is analogous to similar participation in substitution. Just as in substitution, neighboring group intervention in the addition process competes with participation of solvent or added solutes. Groups with the largest driving forces in substitution can be expected to compete the best for involvement in addition reactions. ...