Journal of the American Chemical Society

Sommelet-Hauser Rearrangement of Allylbenzyldimethylammonium Bromide and Cyclopropylcarbinylbenzyldimethylammonium Bromide. Evidence for Carbanion …

CL Bumgardner

文献索引：Bumgardner,C.L. Journal of the American Chemical Society, 1963 , vol. 85, p. 73 - 78

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被引用次数: 19

摘要

Cyclopropylcarbinylbenzyldimethylammoniu... bromide was prepared by treating cyclopropylcarbinyldiinethylaniine in benzene with benzyl bromide. The tertiary amine was obtained by methylation of cyclopropylcarbinylamine~ with formic acid and formaldehyde. The n. ni. r. spectrum of cyclopropylcarbinyldimethylamine prepared in this way indicates that no isomerization occurred during reductive methylation (see Experimental). 3- ...