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Tetrahedron

Conformational studies of tertiary oligo-m-benzanilides and oligo-p-benzanilides in solution

L Chabaud, J Clayden, M Helliwell, A Page, J Raftery…

文献索引:Chabaud, Laurent; Clayden, Jonathan; Helliwell, Madeleine; Page, Abigail; Raftery, James; Vallverdu, Lluis Tetrahedron, 2010 , vol. 66, # 34 p. 6936 - 6957

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被引用次数: 11

摘要

A series of oligo-m-and p-benzanilides were made and their conformations in solution were studied by NMR. In most cases, conformational mixtures were observed as soon as three or more monomers were incorporated into the oligomer. Some crystal structures were obtained, which indicated that helical conformations were adopted in the solid state.