Transition-metal-carbene chemistry. Structure, thermodynamics, and reactivity of rhodium methylidene ion (RhCH2+) in the gas phase

DB Jacobson, BS Freiser

文献索引：Jacobson, D. B.; Freiser, B. S. Journal of the American Chemical Society, 1985 , vol. 107, # 21 p. 5870 - 5876

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被引用次数: 27

摘要

Conclusions The solvent dependence of the tautomeric composition and I3C chemical shifts of D-idose as well as the deuterium isotope effects and the isotopic multiplets all lead to the following simple picture. In going from an aqueous to a nonaqueous solvent, aD- idopyranose, originally present as a mixture of conformers, assumes almost exclusively the 4C, conformation, which is stabilized by intramolecular hydrogen bonding interactions. ...