Canadian Journal of Chemistry

Acid Catalyzed Rearrangements of Conjugated Cyclopropyl and Epoxy Ketones

E Lee-Ruff, P Khazanie

文献索引：Lee-Ruff,E.; Khazanie,P. Canadian Journal of Chemistry, 1975 , vol. 53, p. 1708 - 1713

被引用次数: 11

摘要

A series of spiro [n. 2] alkan-2-ones and their 6 and 7 oxa derivatives were subjected to acid catalysis. In the former series, products arising from hydroxyl (cyclopropyl) carbinyl cations are observed, while in the latter series epoxide oxygen protonation appears to be the dominant reaction pathway. A novel oxavinylcyclopropane rearrangement is reported.

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