Synthesis and spectral properties of the isomeric hydroxybenzo [a] pyrenes

H Yagi, GM Holder, PM Dansette…

文献索引：Yagi,H. et al. Journal of Organic Chemistry, 1976 , vol. 41, # 6 p. 977 - 985

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被引用次数: 55

摘要

Syntheses of the 12 isomeric hydroxybenzo [a] pyrenes are described. Previous syntheses of eight of these iso-mers have been repeated and improved upon. New syntheses of the 1-, 2-, 4-, lo-, and 12-hydroxybenzo [a] pyrenes are reported. Infrared, ultraviolet, fluorescence, and IH NMR spectra of the 12 phenols are provided to facilitate study of the metabolism of this important environmental carcinogen.