Silylation d'hydirocarbures acetyleniques au moyen de chlorosilanes

J Dunogues, P Bourgeois, JP Pillot, G Merault…

文献索引：Dunogues,J. et al. Journal of Organometallic Chemistry, 1975 , vol. 87, p. 169 - 181

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被引用次数: 25

摘要

Abstract The action of the Me 3 SiCl/Mg/HMPT system on various acetylenic hydrocarbons leads by a new route, to mono-, di-or poly-silylated compounds. Most of the derivatives synthetized are new. The persilylation of phenylacetylerie led to a heptasilylated derivative with an unexpected structure, whereas the direct monosilylatmon, which leads to PhC CSiMe 3, can be carried out in satisfactory yields.