Proximity Effects. XXV. Pyrolysis of Cycloöctyl and Cyclodecyl Esters

AC Cope, MJ Youngquist

文献索引：Cope,A.C.; Youngquist,M.J. Journal of the American Chemical Society, 1962 , vol. 84, p. 2411 - 2414

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被引用次数: 5

摘要

The acetates, benzoates, hydrogen phthalates and S-methyl xanthates of cyclooctanol and cyclodecanol have been pyrolyzed, and the pyrolysates have been analyzed with emphasis on the detection of possible transannular products. The acetates and benzoates gave open- chained or, w-dienes and the expected cyclic olefins: small amounts of bicyclic compounds and ring contraction products were formed along with the cyclic olefins from the hydrogen ...