Tetrahedron: Asymmetry

Chiral homoallylic and allylic sulfoxides as models for the stereochemical analysis of sulfoxide thiaoleates

F Daligault, A Arboré, C Nugier-Chauvin, H Patin

文献索引：Daligault, Franck; Arbore, Amelie; Nugier-Chauvin, Caroline; Patin, Henri Tetrahedron Asymmetry, 2004 , vol. 15, # 6 p. 917 - 924

全文：HTML全文

被引用次数: 12

摘要

Both enantiomers of n-butyl allyl sulfoxide have been synthesized and are reported as models of bio-oxidized thiafatty acid analogues. The stereochemical analysis of these aliphatic sulfoxides as well as their homoallylic counterparts, were performed by the use of chiral NMR shift reagents. We first checked the validity of the chiral solvating NMR reagents method using the α-methoxyphenylacetic acid (MPA) and the Pirkle-like alcohol 1-(9- ...