An asymmetric synthesis of (+)-kjellmanianone

D Boschelli, AB Smith, OD Stringer, RH Jenkins…

文献索引：Boschelli; Smith III; Stringer; et al. Tetrahedron Letters, 1981 , vol. 22, # 44 p. 4385 - 4388

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被引用次数: 37

摘要

(+)-Kjellmanianone (l_), member of the cyclopentanoid class of antibiotics, was isolated in 1380 by Nakayama et al'--* from the brown algae, Sargassum kjellmanianum and shown to display moderate activity against such gram positive bacteria as c. _ coli Kl2 and Bacillus subtilis var. niger. The struc--ture, initially derived via chemical and spectroscopic methods, was confirmed by single crystal X-ray analysis, the latter providing in addition the absolute ...