An organometallic route to zinc phosphonates and their intercalates

P Gerbier, C Guérin, B Henner, JR Unal

文献索引：Gerbier, Philippe; Guerin, Christian; Henner, Bernard; Unal, Jean-Remi Journal of Materials Chemistry, 1999 , vol. 9, # 10 p. 2559 - 2565

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被引用次数: 25

摘要

An organometallic non-aqueous route to zinc phosphonates and to their intercalates has been studied. Various phosphonic acids react with dimethylzinc in THF media to afford the corresponding layered zinc phosphonates Zn (O 3 PR 1)(R 1= Me, Ph, 2-and 3-thienyl, thiophen-3-ylmethyl) with evolution of methane. The presence of a primary n-alkylamine in the reaction mixture allows the one-pot formation of 2D-layered intercalated phases of ...