Decyclization of chiorocyclohexanone hydroperoxides under the action of ferrous salts

…, VV Gushchin, AV Ignatenko, AV Aleksandrov…

文献索引：Starostin; Gushchin; Ignatenko; Aleksandrov; Nikishin Russian Chemical Bulletin, 1996 , vol. 45, # 1 p. 133 - 136

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摘要

Abstract The decomposition of 2-chloro-, 2, 2-dichloro-, and 2, 6-dichloro-substituted cyclohexanone hydroperoxides on treatment with ferrous chloride and sulfate to give chloro- substituted aliphatic acids was investigated. A method for the synthesis of 2, 6, 6- trichlorohexanoic and 2, 6, 7, 11-tetrachlorododecane-1, 12-dioic acids was elaborated.