Mercury in organic chemistry. 17. A convenient stereospecific synthesis of enol esters from vinylmercurials

RC Larock, K Oertle, KM Beatty

文献索引：Larock,R.C.; Oertle,K.; Beatty,K.M. Journal of the American Chemical Society, 1980 , vol. 102, p. 1966

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被引用次数: 63

摘要

Abstract: The room temperature reaction of vinylmercurials, mercury carboxylates, and a catalytic amount of palladium acetate provides a novel stereospecific route to a variety of enol carboxylates. The mercuration and subsequent palladium-catalyzed esterification of internal acetylenes afford trans ene diacetates in a convenient one-pot procedure. Lead tetraacetate also reacts with vinylmercurials to afford enol acetates.