Doping metal–organic frameworks for water oxidation, carbon dioxide reduction, and organic photocatalysis

C Wang, Z Xie, KE deKrafft, W Lin

文献索引：Wang, Cheng; Xie, Zhigang; Dekrafft, Kathryn E.; Lin, Wenbin Journal of the American Chemical Society, 2011 , vol. 133, # 34 p. 13445 - 13454

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被引用次数: 481

摘要

Catalytically competent Ir, Re, and Ru complexes H2 L 1–H2 L 6 with dicarboxylic acid functionalities were incorporated into a highly stable and porous Zr6O4 (OH) 4 (bpdc) 6 (UiO- 67, bpdc= para-biphenyldicarboxylic acid) framework using a mix-and-match synthetic strategy. The matching ligand lengths between bpdc and L 1–L 6 ligands allowed the construction of highly crystalline UiO-67 frameworks (metal–organic frameworks (MOFs) 1 ...