Journal of Organometallic Chemistry

The structures of some amides obtained from chloromethyldimethylchlorosilane

RW Hillyard, CM Ryan, CH Yoder

文献索引：Hillyard,R.W. et al. Journal of Organometallic Chemistry, 1978 , vol. 153, p. 369 - 377

全文：HTML全文

被引用次数: 47

摘要

Abstract A series of amides of the type RCONR′[CH 2 Si (CH 3) 2 Cl] were prepared by the reaction of chloromethyldimethylchlorosilane with a series of N-alkyl, N-aryl, and trimethylsilyl amides. The structure of the compound obtained from reaction with bis (trimethylsilyl) acetamide was previously determined by x-ray analysis and is used to rationalize the NMR and IR spectra of its 14 N and 15 SN isotopomers. The spectroscopic ...