The chemistry of carbonyl fluoride. I. The fluorination of organic compounds

FS Fawcett, CW Tullock…

文献索引：Fawcett,F.S. et al. Journal of the American Chemical Society, 1962 , vol. 84, p. 4275 - 4285

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被引用次数: 86

摘要

Carbonyl fluoride is a versatile intermediate to organic fluorine compounds. Its reaction with carbonyl compounds such as cyclohexanone, benzaldehyde and benzophenone gives the gem-difluorides, while N, N-dimethylformamide yields a, a-difluorotrimethylamine. Metal fluoride-catalyzed addition at the ethylenic bond in perfluoroolefins forms perfluoroacyl fluorides, while the C--?! unsaturated compounds CF3X= CF2, CsHsS= CO and CFaC= r': ...