Tetrahedron Letters

Umpolung of reactivity of allylsilane, allylgermane, and allylstannane via their reaction with thallium (III) salt: a new allylation reaction for aromatic compound

M Ochiai, M Arimoto, E Fujita

文献索引：Ochiai, Masahito; Arimoto, Masao; Fujita, Eiichi Tetrahedron Letters, 1981 , vol. 22, # 45 p. 4491 - 4494

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被引用次数: 56

摘要

Abstract A new direct allylation of the aromatic compound has been developed. A combination of allylsilane, allylgermane, or allylstannane and thallium (III) trifluoroacetate gave rise to an allyl cationic species which was allowed to react with an aromatic compound, a nucleophile, to give allylation product (s) in good yields.