Tetrahedron

2H-azirines en milieu acide formation et reactivite d'α-iminocarbeniums

…, S Lacombe, A Laurent, A Maquestiau, B Marquet…

文献索引：Flamming, R.; Lacombe, S.; Laurent, A.; Maquestiau, A.; Marquet, B.; Novkova, S. Tetrahedron, 1986 , vol. 42, # 1 p. 315 - 328

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被引用次数: 8

摘要

Reactivity of protonated azirines is studied in solution and by chemical ionisation in the gazeous phase. Azirinium ion produces an α-iminocarbenium; its reactivity is studied. Mass spectrometry (CID-MIKE technic) proves the rearrangement of the α-iminocarbenium in a nitrilium ion. This nitrilium can also be obtained in solution.