Organotin compounds containing a bulky (Me 3 Si) 3 C or related ligand. Crystal structures of {(Me 3 Si) 3 CMe (O 2 NO) Sn} 2 O,(PhMe 2 Si) 3 CSnMeCl 2 and (PhMe …

SS Al-Juaid, M Al-Rawi, C Eaborn, PB Hitchcock…

文献索引：Al-Juaid, Salih S.; Al-Rawi, Mustafa; Eaborn, Colin; Hitchcock, Peter B.; Smith, J. David Journal of Organometallic Chemistry, 1998 , vol. 564, # 1-2 p. 215 - 226

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被引用次数: 11

摘要

Some compounds having very bulky ligands, mainly (Me3Si) 3C (denoted by Tsi) or (PhMe2Si) 3C (denoted by Tpsi), attached to functional tin centres have been studied. Treatment of TsiSnR2Cl, R= Me or Ph, with one equivalent of ICl gave the corresponding chloride TsiSnRCl2, and use of an excess of ICl gave TsiSnCl3 in both cases. Reaction of either chloride with one equivalent of Br2 gave the dibromide TsiSnRBr2; when an excess ...