Azulene. III. Electrophilic Substitution1-3

AG Anderson Jr, JA Nelson…

文献索引：Anderson et al. Journal of the American Chemical Society, 1953 , vol. 75, p. 4980,4985

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被引用次数: 109

摘要

Friedel-Crafts acetylation of azulene has been shown to give 1-acetylazulene and a diacetylazulene. The structure of the 1-acetylazulene was established by conversion to methyl 1-azuloate. 1-Nitroazulene has been obtained from the treatment of azulene with cupric nitrate and acetic anhydride and reaction of the hydrocarbon with benzenediazonium chloride has been shown to give 1-azuleneazobenzene. These results constitute the first ...