Technetium and rhenium oxo-complexes of new tetradentate ligands with N 2 S 2 and NS 3 donor sets
…, JR Dilworth, DV Griffiths, MJ Al-Jeboori…
文献索引：Archer, Colin M.; Dilworth, Jonathan R.; Griffiths, D. Vaughan; Al-Jeboori, Mohammad J.; Kelly, J. Duncan; Lu, Canzhong; Rosser, Mark J.; Zheng, Yifan Journal of the Chemical Society - Dalton Transactions, 1997 , # 8 p. 1403 - 1410
A series of new tetradentate, nitrogen–sulfur donor proligands with amido or amino donor groups have been synthesized and their rhenium and technetium oxo-complexes prepared. The substitution pattern and length of the ligand backbone can be varied without affecting the co-ordination chemistry. The NS 3 H 3 amido-proligands reacted rapidly with the technetium (V) precursor [TcOCl 4]-at reflux in methanol to give the technetium (IV) ...
