Synthetic applications of 2-phenylselenenylenones. 2. Synthesis of dihydrojasmone and cis-jasmone

D Liotta, CS Barnum, M Saindane

文献索引：Liotta, Dennis; Barnum, Christopher S.; Saindane, Manohar Journal of Organic Chemistry, 1981 , vol. 46, # 21 p. 4301 - 4304

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被引用次数: 29

摘要

In this regard we have shown in a previous study that 2-phenylselenenyl enones undergo 2, 3-dialkylations in high overall yields and that the resulting 2-phenylselenenyl ketones are versatile species which can be selectively converted into a number of different ketones and en one^.^ In this paper we report on the application of this methodology to the synthesis of 1 and 2. Our approach to the synthesis of dihydrojasmone (2) is illustrated in Scheme I. ...