Organometallics

3-Alkylidenethiagermiranes

W Ando, T Tsumuraya

文献索引：Ando, Wataru; Tsumuraya, Takeshi Organometallics, 1989 , vol. 8, p. 1467 - 1472

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被引用次数: 23

摘要

Conclusions We have developed a methodology to prepare the first neutral, monocyclopentadienyllutetium bis (alky1) complexes. Stepwise metathesis of the chlorides in LuCl,(THF),, first with sodium cyclopentadienides and subsequently with lithium alkyls, allows the rational synthesis of this new class of organometallic compound. Earlier results that suggested a strong preference toward the formation of bis (cyclopentadieny1) ...