Tetrahedron: Asymmetry

An efficient route to chiral trans-2, 5-dialkylpyrrolidines via stereoselective intramolecular amidomercuration

H Takahata, H Takehara, N Ohkubo, T Momose

文献索引：Takahata, Hiroki; Takehara, Hiroyuki; Ohkubo, Naoki; Momose, Takefumi Tetrahedron: Asymmetry, 1990 , vol. 1, # 8 p. 561 - 566

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被引用次数: 46

摘要

Download full text in PDF Opens in a new window. Article suggestions will be shown in a dialog on return to ScienceDirect. ... Please enable JavaScript to use all the features on this page. ... An intramolecular amidomercuration of α-butylated 4-pentenylcarbamate 5 predominantly provided trans-2,5-disubstituted pyrrolidine 6, which was elaborated to chiral trans-5-butyl-2-alkylpyrrolidines 10 and 13, constituents of ant venoms. ... A ratio obtained from 270 MHz 1 H NMR ...