Journal of the American Chemical Society

Tungsten-catalyzed allylic alkylations. New avenues for selectivity

BM Trost, MH Hung

文献索引：Trost, Barry M.; Hung, Ming-Hong Journal of the American Chemical Society, 1983 , vol. 105, # 26 p. 7757 - 7759

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被引用次数: 140

摘要

Transition-metal templates offer an opportunity to provide new dimensions for selectivity in organic reactions. In examining the question of regioselectivity of allylic we were intrigued by the possibility of enhanced selectivity for attack at the more substituted end of a n-allyl metal intermediate (eq 1). Five