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Tetrahedron: Asymmetry

Enantioselective synthesis of 3-hydroxycitronellic acid isolated from Ceratocystis fimbriata sp. platani

A Fkyerat, N Burki, R Tabacchi

文献索引:Fkyerat, Abdellatif; Burki, Nicolas; Tabacchi, Raffaele Tetrahedron Asymmetry, 1996 , vol. 7, # 7 p. 2023 - 2028

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被引用次数: 10

摘要

(3S)-and (3R)-3-hydroxy-citronellic acid were obtained by Sharpless epoxidation of geraniol, followed by reduction of the epoxide and subsequent oxidation of the primary alohol to a carboxylic acid. This enantioselective approach allowed us to assign absolute configuration 3R to the naturally occuring monoterpene derivative.