Transition Metal Chemistry

Understanding the electronic and π-conjugation roles of quinoline on ligand substitution reactions of platinum (II) complexes

G Kinunda, D Jaganyi

文献索引：Kinunda, Grace; Jaganyi, Deogratius Transition Metal Chemistry, 2014 , vol. 39, # 4 p. 451 - 459

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被引用次数: 3

摘要

Abstract A kinetic and mechanistic study of chloride substitution by thiourea nucleophiles, namely thiourea, N-methylthiourea, N, N-dimethylthiourea and N, N, N′, N′- tetramethylthiourea in the complexes chlorobis-(2-pyridylmethyl) amineplatinum (II)(Pt1), chloro N-(2-pyridinylmethyl)-8-quinolinamineplatinum (II)(Pt2), chloro N-(2- pyridinylmethylene)-8-quinolinamineplatinum (II)(Pt3) and chlorobis (8-quinolinyl) ...