Tetrahedron

The highly chemoselective transfer hydrogenation of the carbon–carbon double bond of conjugated nitroalkenes by a rhodium complex

J Xiang, EX Sun, CX Lian, WC Yuan, J Zhu, Q Wang…

文献索引：Xiang, Jing; Sun, Er-Xiao; Lian, Chun-Xia; Yuan, Wei-Cheng; Zhu, Jin; Wang, Qiwei; Deng, Jingen Tetrahedron, 2012 , vol. 68, # 24 p. 4609 - 4620

全文：HTML全文

被引用次数: 12

摘要

Chemoselective transfer hydrogenation of conjugated nitroalkenes catalyzed by [RhCl2Cp∗] 2–diamine complex (Cp∗= η5-C5Me5) using HCOOH/Et3N (5: 2)(TEAF) as a hydrogen source was realized. A variety of nitrostyrenes, β-methyl nitrostyrenes, and 3- ...