Reduction of carboxylic acid derivatives using diphenylsilane in the presence of a Rh-PPh3 complex

…, M Kamiya, M Nobutomo, K Kusui, I Furukawa

文献索引：Ohta, Tetsuo; Kamiya, Masahiro; Nobutomo, Mami; Kusui, Keisuke; Furukawa, Isao Bulletin of the Chemical Society of Japan, 2005 , vol. 78, # 10 p. 1856 - 1861

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被引用次数: 51

摘要

Reductions of carboxylic acid derivatives by silanes in the presence of rhodium complexes were studied. Carboxylic esters were reduced to alcohols by diphenylsilane catalyzed by [RhCl (cod)] 2/4PPh 3 or [RhCl (PPh 3) 3] at room temperature in up to 99% yields. For ...