The Journal of Organic Chemistry

Free-radical reactions of fluoroalkanesulfenyl halides. 3. Reactions of fluoroalkane-and chlorofluoroalkanesulfenyl chlorides with hydrocarbons

JF Harris Jr

文献索引：Harris,J.F. Journal of Organic Chemistry, 1979 , vol. 44, p. 563 - 569

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被引用次数: 8

摘要

Free-radical reactions of several fluoroalkane-and chlorofluoroalkanesulfenyl chlorides with toluene. cyclohexane, and butane have been studied. The organic products obtained from these reactions include thiols, disulfides, sulfides, and chlorohydrocarbons. The relative yields of these products depend upon the structure of both the sulfenyl chloride and the hydrocarbon. Steric arguments are proposed to account for the results.