Chemistry of singlet oxygen. 43. Quenching by conjugated olefins

LE Manring, RC Kanner, CS Foote

文献索引：Manring, Lewis E.; Kanner, Richard C.; Foote, Christopher S. Journal of the American Chemical Society, 1983 , vol. 105, # 14 p. 4707 - 4710

全文：HTML全文

被引用次数: 34

摘要

Abstract: The interaction of singlet oxygen with the olefins 2, 5-dimethyl-2, 4-hexadiene (DMHD) and 1-methyl-2-phenylindene (MPI) leads to both reaction and quenching. Although the initial interaction with singlet oxygen is nearly independent of solvent and temperature, the relative amount of quenching depends on solvent in the case of DMHD and on both solvent and temperature in the case of MPI. The increased reaction rate for ...