Canadian Journal of Chemistry

Some cleavage reactions of compounds containing As-As or SS bonds

WR Cullen, PS Dhaliwal

文献索引：Cullen,W.R.; Dhaliwal,P.S. Canadian Journal of Chemistry, 1967 , vol. 45, p. 379 - 382

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被引用次数: 8

摘要

The reaction between diarsines and disulfides to give compounds containing As-S bonds has been further investigated. Compounds with SS bonds are cleaved by (CH3) 2AsH and HCl. CF3SCl cleaves diarsines. Compounds with As-S bonds are cleaved by CF3SCl and (CH3) 2AsH. New compounds obtained are C6H5SAs (CH3) 2, C6H5SSCF3, CH3SSCF3, and C2H5SCH3.