Chlorofluorocarbene: first UV observation of a dihalocarbene in solution

…, J Tian, RR Sauers, C Skalit, K Krogh-Jespersen

文献索引：Moss, Robert A.; Tian, Jingzhi; Sauers, Ronald R.; Skalit, Christopher; Krogh-Jespersen, Karsten Organic Letters, 2007 , vol. 9, # 20 p. 4053 - 4056

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被引用次数: 17

摘要

Chlorofluorocarbene (ClCF), generated by laser flash photolysis of chlorofluorodiazirine, absorbs at 368 nm in pentane. Absolute rate constants are reported for ClCF additions to several alkenes and pyridine. ClCF is less reactive toward alkenes than CCl2, and it does not react rapidly with oxygen. Pertinent computational studies are included.