The Journal of organic chemistry

A tin hydride designed to facilitate removal of tin species from products of stannane-mediated radical reactions

DLJ Clive, J Wang

文献索引：Clive, Derrick L. J.; Wang, Jian Journal of Organic Chemistry, 2002 , vol. 67, # 4 p. 1192 - 1198

全文：HTML全文

被引用次数: 67

摘要

The stannane 1, which is simple to prepare, behaves like the conventional reagents Bu3SnH and Ph3SnH in standard free radical reactions, but with the special characteristic that the tin-containing byproducts are easily and very largely removed by mild hydrolysis (LiOH-water-THF or TsOH-water-THF), which converts them into base-soluble (aqueous NaHCO3) materials. The performance of stannane 1 was evaluated for a range of radical ...