Effects of Structural Changes on the Interconversion of Stereoisomeric Imines. Isoelectronic Models for Vinyl Anions1

DY Curtin, JW Hausser

文献索引：Curtin,D.Y.; Hausser,J.W. Journal of the American Chemical Society, 1961 , vol. 83, p. 3474 - 3481

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被引用次数: 61

摘要

RECEIVED ARCH 13, 1061 ci. sp-Clilorobenzoplienoiie methylimiiie (cis-I) atid trans-P- nitrobenzopheilone methylimine (trans-11) liave beeii obtained as crystalliiie solids and found to rearrange to tlie equilil~ rium mixtures of cis and tram isomers in cyclohexane solu- tim at room temperature and above. Examination of available infrared data suggests that the position of the monosubstituted phenyl absorption in the 700 cm. region may be used to ...