Gas-phase chemistry of transition metal-imido and-nitrene ion complexes. Oxidative addition of nitrogen-hydrogen bonds in ammonia and transfer of NH from a metal …

SW Buckner, JR Gord, BS Freiser

文献索引：Buckner, Steven W.; Gord, James R.; Freiser Ben S. Journal of the American Chemical Society, 1988 , vol. 110, # 20 p. 6606 - 6612

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被引用次数: 88

摘要

Abstract: We report here on the gas-phase chemistry of a number of bare transition metal- nitrene and-imido ion complexes, MNH+. Group 3, 4, and 5 atomic metal ions react with NH, at thermal energies to generate MNH+ via dehydrogenation. A reaction mechanism is proposed involving initial oxidative addition to an NH bond, in analogy to mechanisms proposed for reactions of gaseous atomic metal ions with hydrocarbons. Cr+ reacts with ...