Berninamycin. 2. Products of acidic hydrolysis, methanolysis, and acetolysis of berninamycin A

JM Liesch, DS Millington, RC Pandey…

文献索引：Liesch,J.M. et al. Journal of the American Chemical Society, 1976 , vol. 98, p. 8237 - 8249

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被引用次数: 35

摘要

Abstract: Berninamycin has been separated into berninamycins A and B by countercurrent distribution and by high-pressure liquid chromatography. Acidic hydrolysis of berninamycin A gives berninamycinic acid and the novel amino acid@-hydroxyvaline, as well as threonine, ammonia, and pyruvic acid. Complete reduction of berninamycin A with sodium borohydride followed by acidic hydrolysis gives P-hydroxyvaline, threonine, butyrine, and ...