The Journal of Organic Chemistry

Mechanism of solvolysis reactions of O-methylbenzohydroximoyl halides. Stereoelectronic control in formation of and nucleophilic addition to nitrilium ions

JE Johnson, SC Cornell

文献索引：Johnson, James E.; Cornell, Sravanthi C. Journal of Organic Chemistry, 1980 , vol. 45, p. 4144 - 4148

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被引用次数: 34

摘要

The hydrolysis reactions of the 2 and E isomers of 0-methylbenzohydroximoyl chloride (3a and 2, respectively) have been investigated. The first-order rate constant for the hydrolysis of 3a (1) shows common-ion rate depression,(2) decreases with decreasing concentration of ...