Chemistry Letters

Generation of. BETA.-Keto Radicals from Cyclopropanol Derivatives by the Use of Manganese (III) 2-Pyridinecarboxylate as an Oxidant and Their Reactions with …

N Iwasawa, S Hayakawa, K Isobe, K Narasaka

文献索引：Iwasawa, Nobuharu; Hayakawa, Satoshi; Isobe, Koichi; Narasaka, Koichi Chemistry Letters, 1991 , p. 1193 - 1196

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被引用次数: 35

摘要

Various β-keto radicals are generated from cyclopropanol derivatives such as 1-or 2- substituted cyclopropanols and a cyclopropanone hemiacetal by the use of manganese (III) 2-pyridinecarboxylate, and their reactions with electron-rich olefins give cross-addition products in good yields.