Tetrahedron letters

Palladium-catalysed reductive addition of aryl iodides to aryl and alkylethynylsilanes: A stereo and regioselective route to functionalized 2, 2-disubstituted vinylsilanes

A Arcadi, S Cacchi, F Marinelli

文献索引：Arcadi, A.; Cacchi, S.; Marinelli, F. Tetrahedron Letters, 1986 , vol. 27, # 52 p. 6397 - 6400

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被引用次数: 44

摘要

Abstract Aryl and alkylethynylsilanes are converted into 2, 2-disubstituted vinylsilanes containing various common functional groups in the presence of aryl iodides, a palladium catalyst, formic acid, and a tertiary or secondary amine with high stereoselectivity and good regioselectivity.