Oxiranyl anion methodology using microflow systems

A Nagaki, E Takizawa, J Yoshida

文献索引：Nagaki, Aiichiro; Takizawa, Eiji; Yoshida, Jun-ichi Journal of the American Chemical Society, 2009 , vol. 131, p. 1654 - 1655

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被引用次数: 75

摘要

Deprotonation of epoxides followed by trapping with electrophiles was carried out using microflow systems with varying temperature and residence time. Time-dependence of the yields of products provides a deeper insight into chemical and configurational stabilities of oxiranyllithiums. With the thus-obtained information, reactions of oxiranyllithiums with various electrophiles were successfully carried out without decomposition and ...